| Burke Scott Williams |
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| Associate Professor of Chemistry |
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| Email: |
swilliams@jsd.claremont.edu |
| Office: |
Keck Science Center 227 |
| Phone: |
909-607-1603 |
| Office Hours: |
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| Web Site: |
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| Educational Background: |
| B.S. Harvey Mudd College(Mitsuru Kubota);
M.S., Ph.D. University of Washington (Karen Goldberg);
NSF-NATO Postdoctoral Fellowship, Universiteit Utrecht (Gerard van Koten);
Postdoctoral Fellow, UNC, Chapel Hill (Maurice Brookhart) |
| Courses Taught: |
| General Chemistry,
Organic Chemistry,
Inorganic Chemistry,
Advanced Laboratory in Chemistry |
| Research Interests: |
| Physical Organometallic Chemistry, Ligand Design and Effects on Fundamental Organic Transformations |
| Thesis Topics: |
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| Selected Publications List: Click
to open new window. |
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1.
Benatan, E.; Eppley, H. J.; Geselbracht, M. J.; Johnson, A. R.; Reisner, B. A.; Stewart, J. L.; Watson, L.; Williams, B. S
. (2009). IONiC: A Cyber-Enabled Community of Practice for Improving Inorganic Chemical Education. J. Chem. Ed.
86: 123 (summary).
Abstract
Article
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2.
Smythe, N. A.; Grice, K. A.; Williams, B. S.; Goldberg, K. I
. (2009). Reductive Elimination and Dissociative Beta-Hydride Abstraction from Pt(IV) Hydroxide and Methoxide Complexes. Organometallics
28: 277-288.
Abstract
Article
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3.
Scheuermann, M. L.; Rheingold, A. L.; Williams, B. S.
. (2009). Reversible Carbonylation of an [NCN]PtMe Pincer Complex and Direct Evidence of Alkyl Migration. Organometallics
28: 1613-1615.
Abstract
Article
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4.
Madison, B. L.; Thyme, S. B.; Keene, S.; Williams, B. S
. (2007). Mechanistic Study of Competitive sp3-sp3 and sp2-sp3 Carbon-Carbon Reductive Elimination from a Platinum (IV) Center and the Isolation of a C-C Agostic Complex. J. Am. Chem. Soc.
129: 9538 -9539.
Abstract
Article
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5.
Medici, S.; Gagliardo, M., Williams, S. B.; Chase, P. A.; Gladiali, S.; Lutz, M; Spek, A. L.; van Klink, G. P. M.; van Koten, G
. (2005). Novel P-Stereogenic PCP Pincer-Aryl Ruthenium(II) Complexes and Their Use in the Asymmetric Hydrogen Transfer Reaction of Acetophenone. Helv. Chim. Acta
88: 694 - 705.
Abstract
Article
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6.
Procelewska, J.; Zahl, A.; Liehr, G.; Van Eldik, R.; Smythe, N. A.; Williams, B. S.; Goldberg, K. I.
. (2005). Mechanistic Information on the Reductive Elimination from Cationic Trimethylplatinum(IV) Complexes to Form Carbon-Carbon Bonds. Inorg. Chem.
44: 7732-7742.
Abstract
Article
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7.
Williams, B. S.; Leatherman, M. D.; White, P. S.; Brookhart, M
. (2005). Reactions of Vinyl Acetate and Vinyl Trifluoroacetate with Cationic Diimine Pd(II) and Ni(II) Alkyl Complexes: Identification of Problems Connected with Copolymerizations of These Monomers with Ethylene. J. Am. Chem. Soc.
127: 5132-5146.
Abstract
Article
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8.
Farrington, E. J.; Martinez V. E.; Williams, B. S.; van Koten, G.; Brown, J. M
. (2002). Synthesis and reactivity of a ferrocene-derived PCP-pincer ligand. Chem. Commun.
: 308-309.
Abstract
Article
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9.
Meijer, M. D.; Kleij, A. W.; Williams, B. S.; Ellis, D.; Lutz, M.; Spek, A. L.; van Klink, G. P. M.; van Koten, G
. (2002). Construction of Supported Organometallics Using Cycloplatinated Arylamine Ligands. Organometallics
21: 264-271.
Abstract
Article
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10.
Williams, B. S.; Dani, P.; Lutz, M.; Spek, A. L.; Van Koten, G
. (2001). Development of the first P-stereogenic PCP pincer ligands, their metallation by palladium and platinum, and preliminary catalysis. Helv. Chim. Acta
84: 3519-3530.
Abstract
Article
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11.
Williams, B. S.; Goldberg, K. I
. (2001). Studies of Reductive Elimination Reactions To Form Carbon-Oxygen Bonds from Pt(IV) Complexes. J. Am. Chem. Soc.
123: 2576-2587.
Abstract
Article
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12.
Williams, B. S.; Holland, A. W; Goldberg, K. I
. (1999). Direct Observation of C-O Reductive Elimination from Pt(IV). J. Am. Chem. Soc.
121: 252-253.
Article
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